天山乌苏段火山泥元素组成及含量分析     

尹兆明  姜莹芳  张亚刚  张学敏  张乐涛  王彩云  曹嘉洌  王瑶  方静涵  黄楠楠 《干旱区地理》2017,40(5):1047-1053

采用能量色散型X射线荧光光谱分析（EDXRF）对新疆乌苏天山泥火山土壤样品的元素含量进行了测定。采用单指标评价指数法和内梅罗综合指数法,对新疆天山乌苏段火山泥中的重金属的种类和含量进行了研究,结果显示：Cd、As、Cu元素的含量达到土壤环境质量评价的二级标准,Hg、Pb、Cr、Zn、Ni元素的含量达到土壤环境质量评价的一级标准,乌苏天山火山泥综合评价达到二级标准。将火山泥的元素含量与新疆地区不同土质的土壤元素含量进行比较,与干旱区不同省份的土壤元素含量进行比较,分析了火山泥元素组成及含量的成因。  相似文献   

露天煤矿周围的四种植被重金属富集和转移特征分析     

阿不都艾尼&#  阿不里  塔西甫拉提&#  特依拜  玉米提&#  哈力克  师庆东  尼格拉&#  塔西甫拉提  塔依尔江&#  艾山  阿尔祖娜&#  阿布力米提 《干旱区地理》2017,40(6):1207-1217

采用野外调查和室内化学分析相结合的方法,对新疆准东露天煤矿周围常见的假木贼（Anabasis aphylla）、梭梭（Haloxylon ammodendron）、琵琶柴（Reaumuria songoonica）、蛇麻黄（Ephedradistachya）等四种植物对重金属的吸收、富集能力和来源进行了分析。结果表明：植物体内重金属含量大小来看,Zn、Cu、Cr含量较大,Pb、As和Hg含量较少。假木贼根部的Cr含量以及四种植被体内Hg含量均超过了植被生长的正常范围。从植物与相应土壤中的重金属相关性来看,假木贼,琵琶柴体内Zn、Cu元素,琵琶柴体内Zn、Hg、As元素,梭梭体内的Zn、Cu、As元素与相应土壤中的重金属含量相关性较好,植物体内的重金属主要来自于土壤,交通运输,大气降尘等多种来源。植物对重金属的富集和转移能力表明,假木贼（2.89）,琵琶柴（1.14）,梭梭（1.72）对Hg有一定的富集能力,其富集能力大小顺序为假木贼>梭梭>琵琶柴,它们属于潜在的Hg富集植物。蛇麻黄对Cu具有较强富集能力。假木贼,琵琶柴和梭梭对Zn、Cr和Pb具有较好的转移能力。这三种植物对重金属均有一定的耐性,可作为矿区土壤植物修复的优选物种。  相似文献   

Hydrogeochemical characteristics of mine water in the Harz Mountains,Germany     

《Chemie der Erde / Geochemistry》2017,77(4):614-624

Water samples (springs, creeks, mine adits) from different former mining districts of the Harz Mountains and the nearby Kupferschiefer (copper shale) basin of Sangerhausen were analysed for major ions and trace metals. Due to more intensive water rock interactions including the ore minerals, the mine water concentrations of main components and trace metals are generally higher compared to non mining affected surface waters of the mountain range. Furthermore, the content of major ions in mine water is enriched by mixing processes with saline waters from Permian layers in the Kupferschiefer district and at the deeper levels of the mines in the Upper Harz Mountains. The waters of the different mining districts can be distinguished by trace metal occurrences and concentrations derived from the different ore bodies. Water from the Kupferschiefer mines shows the highest Na, Cl, Cu, Mo and U concentrations, whereas a combination of elevated As and Se concentrations is typical for most of the samples from the mines around St. Andreasberg. However, there are exceptions, and some water samples of all the investigated mining districts do not follow these general trends. Despite the influence of mining activities and ore mineralisation, hydrochemical effects due to rain water dilution can be seen in most of the waters. According to the elevation of the mountain range, higher precipitation rates decrease the ion concentrations in the waters of springs, creeks and mine adits.  相似文献   

Cenozoic metallogeny of Greece and potential for precious,critical and rare metals exploration     

《Ore Geology Reviews》2017

The Cenozoic metallogeny in Greece includes numerous major and minor hydrothermal mineral deposits, associated with the closure of the Western Tethyan Ocean and the collision with the Eurasian continental plate in the Aegean Sea, which started in the Cretaceous and is still ongoing. Mineral deposits formed in four main periods: Oligocene (33–25 Ma), early Miocene (22–19 Ma), middle to late Miocene (14–7 Ma), and Pliocene-Pleistocene (3–1.5 Ma). These metallogenic periods occurred in response to slab-rollback and migration of post-collisional calc-alkaline to shoshonitic magmatism in a back-arc extensional regime from the Rhodopes through the Cyclades, and to arc-related magmatism along the active south Aegean volcanic arc. Invasion of asthenospheric melts into the lower crust occurred due to slab retreat, and were responsible for partial melting of metasomatized lithosphere and lower crustal cumulates. These geodynamic events took place during the collapse of the Hellenic orogen along large detachment faults, which exhumed extensive metamorphic core complexes in mainly two regions, the Rhodopes and the Cyclades. The detachment faults and supra-detachment basins controlled magma emplacement, fluid circulation, and mineralization.The most significant mineralization styles comprise porphyry, epithermal, carbonate-replacement, reduced intrusion-related gold, intrusion-related Mo-W and polymetallic veins. Porphyry and epithermal deposits are commonly associated with extensive hydrothermal alteration halos, whereas in other cases alteration is of restricted development and mainly structurally controlled. Porphyry deposits include Cu-Au-, Cu-Mo-Au-Re, Mo-Re, and Mo-W variants. Epithermal deposits include mostly high- and intermediate-sulfidation (HS and IS) types hosted in volcanic rocks, although sedimentary and metamorphic rock hosted mineralized veins, breccias, and disseminations are also present. The main metal associations are Cu-Au-Ag-Te and Pb-Zn-Au-Ag-Te in HS and IS epithermal deposits, respectively. Major carbonate-replacement deposits in the Kassandra and Lavrion mining districts are rich in Au and Ag, and together with reduced intrusion-related gold systems played a critical role in ancient economies. Finally hundreds of polymetallic veins hosted by metamorphic rocks in the Rhodopes and Cyclades significantly add to the metal endowment of Greece.  相似文献   

The rare earth element (REE) mineralisation potential of highly fractionated rhyolites: A potential low-grade,bulk tonnage source of critical metals     

《Ore Geology Reviews》2017

The rare earth elements (REE) have become crucial for modern industry, technology and medicine, with the increase in demand for these elements over the past few years currently being met by relatively few well-known mineral deposits. This lack of a secure supply of the REE has led to increased research into potential alternative sources of these in demand elements. The primary fractionation processes involved in the petrogenesis of highly fractionated high-silica rhyolites can cause the magmas that form these units to become preferentially enriched in the REE, especially in the more valuable heavy REE (HREE), although this is dependent on the mineral assemblages fractionated by the system in question, a factor that is in turn a function of the source and tectonic setting of a given magmatic event. The mineralogy of the REE is also important, with volatile exsolution and vapour-phase activity within highly evolved rhyolite systems potentially having a key role in concentrating the REE and other elements into concentrations (and more importantly potentially acid leachable and therefore processable minerals) that may be economically viable to extract. This, combined with the fact these rhyolites are often enriched in other critical and/or economically important metals (e.g., Y, Nb, Ta, Be, Li, F, Sn, Rb, Th, and U) means that these volcanic units should be considered as potential sources of these critical metals. In addition, the large volume nature of these rhyolites combined with the fact they frequently crop out at the Earth’s surface makes them ideally suited for more economical bulk open pit extraction. This suggests that these high-silica REE-enriched rhyolites should be considered potential REE analogues of bulk-tonnage, low-grade porphyry Cu deposits, warranting further investigation to determine whether these rhyolites are a viable new source of the REE (especially the HREE) and are potential targets for future mineral exploration.  相似文献   

In situ Pb and bulk Sr isotope analysis of the Yinchanggou Pb-Zn deposit in Sichuan Province (SW China): Constraints on the origin and evolution of hydrothermal fluids     

《Ore Geology Reviews》2017

The Yinchanggou Pb-Zn deposit, located in southwestern Sichuan Province, western Yangtze Block, is stratigraphically controlled by late Ediacaran Dengying Formation and contains >0.3 Mt of metal reserves with 11 wt% Pb + Zn. A principal feature is that this deposit is structurally controlled by normal faults, whereas other typical deposits nearby (e.g. Maozu) are controlled by reverse faults. The origin of the Yinchanggou deposit is still controversial. Ore genetic models, based on conventional whole-rock isotope tracers, favor either sedimentary basin brine, magmatic water or metamorphic fluid sources. Here we use in situ Pb and bulk Sr isotope features of sulfide minerals to constrain the origin and evolution of hydrothermal fluids. The Pb isotope compositions of galena determined by femtosecond LA-MC-ICPMS are as follows: ²⁰⁶Pb/²⁰⁴Pb = 18.17–18.24, ²⁰⁷Pb/²⁰⁴Pb = 15.69–15.71, ²⁰⁸Pb/²⁰⁴Pb = 38.51–38.63. These in situ Pb isotope data overlap with bulk-chemistry Pb isotope compositions of sulfide minerals (²⁰⁶Pb/²⁰⁴Pb = 18.11–18.40, ²⁰⁷Pb/²⁰⁴Pb = 15.66–15.76, ²⁰⁸Pb/²⁰⁴Pb = 38.25–38.88), and both sets of data plotting above the Pb evolution curve of average upper continental crust. Such Pb isotope signatures suggest an upper crustal source of Pb. In addition, the coarse-grained galena in massive ore collected from the deep part has higher ²⁰⁶Pb/²⁰⁴Pb ratios (18.18–18.24) than the fine-grained galena in stockwork ore sampled from the shallow part (²⁰⁶Pb/²⁰⁴Pb = 18.17–18.19), whereas the latter has higher ²⁰⁸Pb/²⁰⁴Pb ratios (38.59–38.63) than the former (²⁰⁸Pb/²⁰⁴Pb = 38.51–38.59). However, both types of galena have the same ²⁰⁷Pb/²⁰⁴Pb ratios (15.69–15.71). This implies two independent Pb sources, and the metal Pb derived from the basement metamorphic rocks was dominant during the early phase of ore formation in the deep part, whereas the ore-hosting sedimentary rocks supplied the majority of metal Pb at the late phase in the shallow part. In addition, sphalerite separated from different levels has initial ⁸⁷Sr/⁸⁶Sr ratios ranging from 0.7101 to 0.7130, which are higher than the ore formation age-corrected ⁸⁷Sr/⁸⁶Sr ratios of country sedimentary rocks (⁸⁷Sr/⁸⁶Sr_200 Ma = 0.7083–0.7096), but are significantly lower than those of the ore formation age-corrected basement rocks (⁸⁷Sr/⁸⁶Sr_200 Ma = 0.7243–0.7288). Again, such Sr isotope signatures suggest that the above two Pb sources were involved in ore formation. Hence, the gradually mixing process of mineralizing elements and associated fluids plays a key role in the precipitation of sulfide minerals at the Yinchanggou ore district. Integrating all the evidence, we interpret the Yinchanggou deposit as a strata-bound, normal fault-controlled epigenetic deposit that formed during the late Indosinian. We also propose that the massive ore is formed earlier than the stockwork ore, and the temporal-spatial variations of Pb and Sr isotopes suggest a certain potential of ore prospecting in the deep mining area.  相似文献   

经济发展梯度影响下的江苏农用地土壤重金属含量分布格局   总被引：4，自引：3，他引：1  

吴绍华  周生路  张红富  赵其国 《地理科学》2008,28(3)

根据江苏省农用地22个标准样地的7种重金属元素含量测定结果,应用TWINSPAN分类、CCA排序的多元统计方法,对江苏农用地耕作层土壤重金属元素含量格局和影响因子进行了定量分析.研究结果表明,江苏耕作层土壤重金属元素含量整体特征具有明显的沿经济发展梯度(苏南-苏中-苏北)的递减格局.空间位置、人类活动强度、土壤理化性质是控制梯度分布格局重要的环境因素,通过变量分离,空间变量解释的部分占21.5%,人为活动变量解释部分占17.9%,理化性质变量解释部分占17.5%,三组变量总解释量占56.9%,不能解释部分占43.1%.人类活动与空间位置因素一起可以综合反映江苏经济发展的空间梯度,其占了总解释量的69.2%,经济发展梯度对农用地重金属元素含量有着深刻的影响.  相似文献   

Hazardous Heavy Metal Distribution in Dahuofang Catchment,Fushun, Liaoning,an Important Industry City in China: A Case Study     

Gang Wu  Ji‐You Wu  Hong‐Bo Shao 《洁净——土壤、空气、水》2012,40(12):1372-1375

Located in Liaoning Province, one of the traditional heavy industrial areas in China, Dahuofang Reservoir provides drinking water for nearly 30 000 000 citizens, as well as industrial and agricultural water for dozens of several cities and rural areas. The distribution of hazardous heavy metals is described in several types of soil, crops, and in different industrial or mining areas and main sewage irrigation areas. Five possible reasons that may cause the pollution are analyzed and listed. Also we provide some pragmatic suggestions for the remediation of heavy metals in contaminated soils.  相似文献   

Study of the Interaction Mechanism in the Biosorption of Copper(II) Ions onto Posidonia oceanica and Peat     

Marta Izquierdo  Paula Marzal  Carmen Gabaldón  Margherita Silvetti  Paola Castaldi 《洁净——土壤、空气、水》2012,40(4):428-437

A systematic approach was used to characterize the biosorption of copper(II) onto two biosorbents, Posidonia oceanica and peat, focusing on the interaction mechanisms, the copper(II) sorption–desorption process and the thermal behavior of the biosorbents. Sorption isotherms at pH 4–6 were obtained and the experimental data were fitted to the Langmuir model with a maximum uptake (q_max) at pH 6 of 85.78 and 49.69 mg g^?1, for P. oceanica and peat, respectively. A sequential desorption (SD) with water, Ca(NO₃)₂, and EDTA was applied to copper‐saturated biosorbents. Around 65–70% copper(II) were desorbed with EDTA, indicating that this heavy metal was strongly bound. The reversibility of copper(II) sorption was obtained by desorption with HCl and SD. Fourier transform IR spectroscopy (FTIR) analysis detected the presence of peaks associated with OH groups in aromatic and aliphatic structures, CH, CH₂, and CH₃ in aliphatic structures, COO^? and COOH groups and unsaturated aromatic structures on the surface of both biosorbents, as well as peaks corresponding to Si? O groups on the surface of peat. The results of SEM‐EDX and FTIR analysis of copper‐saturated samples demonstrated that ion exchange was one of the mechanisms involved in copper(II) retention. Thermal analysis of biosorbent samples showed that copper(II) sorption–desorption processes affected the thermal stability of the biosorbents.  相似文献   

Provenance discrimination and Source-to-Sink studies from a dryland fluvial regime： An example from Kachchh,western India     

S. P. PRIZOMWALA  Nilesh BHATT  N. BASAVAIAH 《国际泥沙研究》2014,29(1):99-109

Tracing the sediment delivery from its source terrain to its ultimate sink envisage multiple factors that play a vital role in understanding present day erosional engine.To accomplish this,it is significant to distinguish the variable end-members contributing to the basin.The findings from the study of dryland coastal fluvial regime in Kachchh(Western India),which is one of the end members contributing to the Gulf of Kachchh coast(partial sink) and finally to the Arabian Sea(ultimate sink) have been presented here.Multi-proxy sediment provenance proxies such as grain-size,clay minerals,geochemistry and magnetic minerals have been employed to evaluate the provenance discriminating characteristics of the Kachchh dryland fluvial system and factors influencing them.The results of different proxies indicate that the provenance signatures of uplands are quite characteristic with magnetic susceptibility(χ) values of 20×10~(-7)m~3kg~(-1) and smectite(S)/kaolinite(K) ratio between 0.26 and 0.49.The middle reaches show marked increase in magnetic mineral concentration with χ values(140×10~(-7)m~3kg~(-1))and S/K ratio(4.92),while the estuarine tract shows χ values(80×10~(-7)m~3kg~(-1)),S/K ratio(1.90) and,characteristic heavy minerals(i.e.mica minerals),probably reflect the interplay between land and sea oscillations.Major sources of sediments within catchment scale were identified,viz.,upland sedimentary rocks(Juran and Bhuj Formation sandstone-shale) and middle reaches volcanic(Deccan Trap Formation basalt) rocks.The present study draw cautions in provenance of sediment discrimination in areas influenced by Deccan basalt that has the overwhelming sediment delivery and a comparatively subdued effects of other provenance signatures.The studied proxies of mineralogy of clays,magnetic minerals and geochemistry of heavy and major elements serve as the potential for fingerprint of sediment source regions and hence behold a strong position in source to sink studies globally.  相似文献